Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles

Zhi Cun Wang, Boya Kuang, Hanyuan Chen, Nicolas Bogliotti, Ran Guo, Yan Liu, Jin Xiu Zhou*, Mu Hua Huang*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (kapp = 0.965 min−1) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).

源语言英语
期刊Nanoscale
DOI
出版状态已接受/待刊 - 2025
已对外发布

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