摘要
Lithium-ion batteries (LIBs) face capacity degradation and safety risks from internal gas evolution. This study compares differential electrochemical mass spectrometry (DEMS) and in-situ non-dispersive infrared (NDIR) gas sensors for monitoring gas in graphite/NMC811 batteries. DEMS enables real-time gas detection but relies on carrier gases and causes 49.7 % capacity loss in small cells. NDIR sensors in 800 mAh pouch cells offer continuous, non-destructive monitoring with <1 % capacity loss, detecting gas accumulation and consumption. NDIR proves robust for operando gas monitoring in high-capacity LIBs, aiding failure mechanism analysis and safety improvement.
源语言 | 英语 |
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文章编号 | 142284 |
期刊 | Chemical Physics Letters |
卷 | 876 |
DOI | |
出版状态 | 已出版 - 10月 2025 |
已对外发布 | 是 |