TY - JOUR
T1 - Bio-Inspired Consecutive Photocatalyzed C-H Nitration of Arenes
AU - An, Da Lie
AU - Xu, Chao
AU - Wang, Manman
AU - Shu, Qinghai
AU - Zhou, Xukai
N1 - Publisher Copyright:
© 2025 American Chemical Society.
PY - 2025/3/28
Y1 - 2025/3/28
N2 - Concerned with traditional nitration methods requiring high temperatures, strong acids, or oxidizing agents, we developed an acid-free, selective photocatalytic nitration method using riboflavin tetraacetate and Fe(NO3)3·9H2O under visible light. This method efficiently nitrates various arenes and bioactive molecules with high selectivity and functional group tolerance, offering a sustainable alternative to traditional nitration techniques.
AB - Concerned with traditional nitration methods requiring high temperatures, strong acids, or oxidizing agents, we developed an acid-free, selective photocatalytic nitration method using riboflavin tetraacetate and Fe(NO3)3·9H2O under visible light. This method efficiently nitrates various arenes and bioactive molecules with high selectivity and functional group tolerance, offering a sustainable alternative to traditional nitration techniques.
UR - http://www.scopus.com/pages/publications/105001499029
U2 - 10.1021/acs.joc.5c00024
DO - 10.1021/acs.joc.5c00024
M3 - Article
AN - SCOPUS:105001499029
SN - 0022-3263
VL - 90
SP - 4313
EP - 4324
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 12
ER -