Spin-state modulation by host-guest chemistry with cucurbiturils

Ke Lu; Yu Xiao Chen; Jie Sheng Hu; Zhi Kun Liu; Xin Li Shi; Meng Yu; Alyona A. Starikova; Jun Tao

doi:10.1039/d5cc00979k

Spin-state modulation by host-guest chemistry with cucurbiturils

Ke Lu, Yu Xiao Chen, Jie Sheng Hu, Zhi Kun Liu, Xin Li Shi, Meng Yu^*, Alyona A. Starikova^*, Jun Tao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(ii)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT_1/2 = 77 K) via secondary coordination sphere perturbations.

Original language	English
Pages (from-to)	7137-7140
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	39
DOIs	http://doi.org/10.1039/d5cc00979k
Publication status	Published - 11 Apr 2025
Externally published	Yes

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title = "Spin-state modulation by host-guest chemistry with cucurbiturils",

abstract = "The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(ii)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbations.",

author = "Ke Lu and Chen, \{Yu Xiao\} and Hu, \{Jie Sheng\} and Liu, \{Zhi Kun\} and Shi, \{Xin Li\} and Meng Yu and Starikova, \{Alyona A.\} and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = apr,

day = "11",

doi = "10.1039/d5cc00979k",

language = "English",

volume = "61",

pages = "7137--7140",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Spin-state modulation by host-guest chemistry with cucurbiturils

AU - Lu, Ke

AU - Chen, Yu Xiao

AU - Hu, Jie Sheng

AU - Liu, Zhi Kun

AU - Shi, Xin Li

AU - Yu, Meng

AU - Starikova, Alyona A.

AU - Tao, Jun

PY - 2025/4/11

Y1 - 2025/4/11

N2 - The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(ii)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbations.

AB - The host-guest binding of cucurbit[7]uril to a methylpyridinium-functionalized Co(ii)-terpyridine complex shifts the spin equilibrium to the low-spin state (ΔT1/2 = 77 K) via secondary coordination sphere perturbations.

UR - http://www.scopus.com/pages/publications/105003434055

U2 - 10.1039/d5cc00979k

DO - 10.1039/d5cc00979k

M3 - Article

AN - SCOPUS:105003434055

SN - 1359-7345

VL - 61

SP - 7137

EP - 7140

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Spin-state modulation by host-guest chemistry with cucurbiturils

Abstract

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