Asymmetric Dual-Atomic Catalyst with Axial Chloride Coordination for Efficient Oxygen Reduction Reaction

Yan Zhang; Fuhua Li; Shuwei Li; Zedong Zhang; Zhiyi Sun; Yuhai Dou; Rui Su; Yahe Wu; Liang Zhang; Wenxing Chen; Dingsheng Wang; Yadong Li

doi:10.1002/adma.202507478

Asymmetric Dual-Atomic Catalyst with Axial Chloride Coordination for Efficient Oxygen Reduction Reaction

Yan Zhang, Fuhua Li, Shuwei Li, Zedong Zhang^*, Zhiyi Sun, Yuhai Dou, Rui Su, Yahe Wu^*, Liang Zhang^*, Wenxing Chen^*, Dingsheng Wang, Yadong Li

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Low-platinum-group metal (low-PGM) catalysts play a crucial role in reducing the cost of proton exchange membrane fuel cells (PEMFCs). Dual-atomic catalysts offer valuable solutions due to their exceptional performance. This work explores the application of axial Cl-coordinated Pt─Co dual atoms on N-doped graphitic carbon (Pt₁Co₁/NC─Cl) catalysts utilizing PtCo dual-atomic catalysts, demonstrating their ability to significantly enhance the acidic oxygen reduction reaction (ORR) catalytic performance of conventional PtCo catalysts. The half-wave potential (E_1/2) reaches 0.841 V in a 0.1 M HClO₄ solution, and only a reduction of 12 mV in E_1/2 is observed after 5000 cycles. Axial Cl proves to be resistant to removal during the electroreduction reaction. Consequently, the use of heteroatom-modulated asymmetric structures can greatly improve the performance of Pt-based catalysts. Incorporating nonmetallic synergistic Pt-group metals presents a promising solution for achieving high-performance Low-PGMs.

Original language	English
Journal	Advanced Materials
DOIs	http://doi.org/10.1002/adma.202507478
Publication status	Accepted/In press - 2025
Externally published	Yes

Keywords

asymmetric dual-atomic catalyst
axial chloride coordination
low-platinum-group metal catalysts
oxygen reduction reaction

Access to Document

10.1002/adma.202507478

Cite this

@article{e150452f86c842cb8426827a4bde7b24,

title = "Asymmetric Dual-Atomic Catalyst with Axial Chloride Coordination for Efficient Oxygen Reduction Reaction",

abstract = "Low-platinum-group metal (low-PGM) catalysts play a crucial role in reducing the cost of proton exchange membrane fuel cells (PEMFCs). Dual-atomic catalysts offer valuable solutions due to their exceptional performance. This work explores the application of axial Cl-coordinated Pt─Co dual atoms on N-doped graphitic carbon (Pt1Co1/NC─Cl) catalysts utilizing PtCo dual-atomic catalysts, demonstrating their ability to significantly enhance the acidic oxygen reduction reaction (ORR) catalytic performance of conventional PtCo catalysts. The half-wave potential (E1/2) reaches 0.841 V in a 0.1 M HClO4 solution, and only a reduction of 12 mV in E1/2 is observed after 5000 cycles. Axial Cl proves to be resistant to removal during the electroreduction reaction. Consequently, the use of heteroatom-modulated asymmetric structures can greatly improve the performance of Pt-based catalysts. Incorporating nonmetallic synergistic Pt-group metals presents a promising solution for achieving high-performance Low-PGMs.",

keywords = "asymmetric dual-atomic catalyst, axial chloride coordination, low-platinum-group metal catalysts, oxygen reduction reaction",

author = "Yan Zhang and Fuhua Li and Shuwei Li and Zedong Zhang and Zhiyi Sun and Yuhai Dou and Rui Su and Yahe Wu and Liang Zhang and Wenxing Chen and Dingsheng Wang and Yadong Li",

note = "Publisher Copyright: {\textcopyright} 2025 Wiley-VCH GmbH.",

year = "2025",

doi = "10.1002/adma.202507478",

language = "English",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Asymmetric Dual-Atomic Catalyst with Axial Chloride Coordination for Efficient Oxygen Reduction Reaction

AU - Zhang, Yan

AU - Li, Fuhua

AU - Li, Shuwei

AU - Zhang, Zedong

AU - Sun, Zhiyi

AU - Dou, Yuhai

AU - Su, Rui

AU - Wu, Yahe

AU - Zhang, Liang

AU - Chen, Wenxing

AU - Wang, Dingsheng

AU - Li, Yadong

PY - 2025

Y1 - 2025

N2 - Low-platinum-group metal (low-PGM) catalysts play a crucial role in reducing the cost of proton exchange membrane fuel cells (PEMFCs). Dual-atomic catalysts offer valuable solutions due to their exceptional performance. This work explores the application of axial Cl-coordinated Pt─Co dual atoms on N-doped graphitic carbon (Pt1Co1/NC─Cl) catalysts utilizing PtCo dual-atomic catalysts, demonstrating their ability to significantly enhance the acidic oxygen reduction reaction (ORR) catalytic performance of conventional PtCo catalysts. The half-wave potential (E1/2) reaches 0.841 V in a 0.1 M HClO4 solution, and only a reduction of 12 mV in E1/2 is observed after 5000 cycles. Axial Cl proves to be resistant to removal during the electroreduction reaction. Consequently, the use of heteroatom-modulated asymmetric structures can greatly improve the performance of Pt-based catalysts. Incorporating nonmetallic synergistic Pt-group metals presents a promising solution for achieving high-performance Low-PGMs.

AB - Low-platinum-group metal (low-PGM) catalysts play a crucial role in reducing the cost of proton exchange membrane fuel cells (PEMFCs). Dual-atomic catalysts offer valuable solutions due to their exceptional performance. This work explores the application of axial Cl-coordinated Pt─Co dual atoms on N-doped graphitic carbon (Pt1Co1/NC─Cl) catalysts utilizing PtCo dual-atomic catalysts, demonstrating their ability to significantly enhance the acidic oxygen reduction reaction (ORR) catalytic performance of conventional PtCo catalysts. The half-wave potential (E1/2) reaches 0.841 V in a 0.1 M HClO4 solution, and only a reduction of 12 mV in E1/2 is observed after 5000 cycles. Axial Cl proves to be resistant to removal during the electroreduction reaction. Consequently, the use of heteroatom-modulated asymmetric structures can greatly improve the performance of Pt-based catalysts. Incorporating nonmetallic synergistic Pt-group metals presents a promising solution for achieving high-performance Low-PGMs.

KW - asymmetric dual-atomic catalyst

KW - axial chloride coordination

KW - low-platinum-group metal catalysts

KW - oxygen reduction reaction

UR - http://www.scopus.com/pages/publications/105007155901

U2 - 10.1002/adma.202507478

DO - 10.1002/adma.202507478

M3 - Article

AN - SCOPUS:105007155901

SN - 0935-9648

JO - Advanced Materials

JF - Advanced Materials

ER -

Asymmetric Dual-Atomic Catalyst with Axial Chloride Coordination for Efficient Oxygen Reduction Reaction

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this